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Faculty of Sciences
Document Details
Document Type
:
Article In Journal
Document Title
:
Chemical equilibria and sequential extractive spectrophotometric determination of selenium(IV) and (VI) using the chromogenic reagent 4,4 '-dichlorodithizone
Chemical equilibria and sequential extractive spectrophotometric determination of selenium(IV) and (VI) using the chromogenic reagent 4,4 '-dichlorodithizone
Document Language
:
Arabic
Abstract
:
The chromogenic reagent 4,4-dichloro(3-mercapto-1,5-diphenylformazan), Cl2H2DZ, forms a yellow-red-coloured complex with selenium(IV). The produced complex species was extracted quantitatively into n-hexane, and its absorbance was measured at 416 nm. The chemical composition of the extracted selenium(IV)-Cl2H2DZ chelate and the molar absorptivity at 416 nm were found to be [SeO (Cl2HDZ)(2)] and 9 x 10(4) L mol(-1) cm(-1), respectively. The values of the extraction constants (K-D, K-ex, beta) enable a convenient application of the proposed system for the liquid - liquid extraction procedure and sequential spectrophotometric determination of traces of inorganic selenium( IV) and/or selenium( VI) after reduction of the later to selenium( IV) with HCl ( 6 M). Beers law and Ringboms plots were obeyed in the concentration range 0.01 - 20 and 0.5 - 19 mu g mL(-1) of selenium(IV), respectively, with a relative standard deviation of 2.2%. The proposed method has been successfully applied to the determination of selenium( IV) or ( VI) and total inorganic selenium( IV) and ( VI) in tap and freshwater samples.
Journal Name
:
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
Volume
:
86
Issue Number
:
12
Publishing Year
:
2006 AH
Added Date
:
Tuesday, June 17, 2008
Researchers
Researcher Name (Arabic)
Researcher Name (English)
Researcher Type
Dr Grade
Email
محمد سرور الشهاوي
El-Shahawi, Mohammad S
Researcher
.
Othman, Abdelhameed M
Researcher
عبد العزيز صالح باشماخ
Bashammakh, Abdulaziz S
Researcher
.
El-Sonbati, Mervat A
Researcher
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